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In this category, cis -6-(2-acetylvinylthio)-purine (cAVTP) and trans -6-(2-acetylvinylthio)-guanine (tAVTG) contain active thiopurines (6-mercaptopurine and 6-thioguanine, respectively) liberated intracellularly after GSH-conjugation catalyzed by GST M1-1, M2-2, and A4-4, but not GST P1-1 (Gunnarsdottir et al., 2002
Therapeutic peptides are lab-made versions of these natural signaling molecules
Helsinn Healthcare conducted clinical development for postoperative GI motility (ipamorelin was investigated as a GI prokinetic given its partial GI tract action through peripheral GHSR-1a), but no NDA was filed
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