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PMID: 20190196 Reported Macrocycle stability Lactam-bridged backbone confers proteolytic stability The side-chaintoside-chain lactam bridge between Asp(2) and Lys(7) is reported in macrocyclization-strategies reviews to confer proteolytic stability relative to linear -MSH and to constrain the receptor-binding pharmacophore (the conserved His-Phe-Arg-Trp / HFRW core, with D-Phe at position 4 of the cycle in PT-141)
[2] GHK peptide as a natural modulator of multiple cellular pathways in skin regeneration NIH / PMC
That approach that could make enforcement more efficient as telehealth platforms scale distribution of pharmacy-made drugs
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