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Lactate, the common substrate for both pathways, exists as two isomers, L-lactate and D-lactate, with L-lactate participating in enzymatic Kla and D-lactate in non-enzymatic processes ( Using L-lactate as a substrate, solvent-exposed lysine residues exhibit nucleophilic reactivity owing to their -amino groups chemical flexibility

doi:10.1016/j.isci.2020.101116

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Tyrosinase the rate-limiting enzyme in melanin synthesis is inhibited by glutathione