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IV delivery bypasses this entirely, achieving near 100% bioavailability and distributing glutathione directly to tissues
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The side-chain guanidyl group of Arg454 interacts with the carboxylate moiety of glycine to orient the substrate for attack on the acyl-phosphate intermediate (Herrera et al., Unlike other organisms, some plants synthesize glutathione analogs in which -alanine, serine, or glutamate replaces glycine in the tripeptide (Figure 4A)
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Glutathione peroxidase
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