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(1) The peptide is posited to modulate a coordinated network of matrix degradation and synthesis, possibly by concurrently upregulating collagen, glycosaminoglycans, matrix metalloproteinases (MMPs), and tissue inhibitors of metalloproteinases (TIMPs)

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Electrospray of a coordination complex is unreliable in a way that catches people out: the complex can dissociate in the source, so the ion you observe may well be the free tripeptide rather than the copper adduct

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