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Storage conditions that shorten unopened shelf life: heat (extended exposure above 25C), freezing and re-thawing (can crack the stopper seal), direct sunlight (degrades benzyl alcohol), and humid environments (can degrade label readability and obscure exp date)

This depends on the specific peptide and your protocol

The peptide dissolves readily at pH values achievable with water, and the absence of salts minimizes ionic interactions during initial dissolution