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Different routes affect tissue exposure, signaling, and outcomes

The side-chain guanidyl group of Arg454 interacts with the carboxylate moiety of glycine to orient the substrate for attack on the acyl-phosphate intermediate (Herrera et al., Unlike other organisms, some plants synthesize glutathione analogs in which -alanine, serine, or glutamate replaces glycine in the tripeptide (Figure 4A)

This dual mechanism provides enhanced benefits in blood sugar control and weight reduction compared to GLP-1 agonists alone