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NAD+ doesn't do any of this
When the energy charge is low, CoASH is not acetylated, therefore, pyruvate carboxylase is inactive, and pyruvate is preferentially oxidized to acetyl-CoA via the PDHc
Liu S, Chen B, Feng Y, Gao C, Du D, Jiang T, et al
Calabrese V, Stella AM, Butterfield DA, Scapagnini G (2005) Redox regulation in neurodegeneration and longevity: role of the heme oxygenase and HSP70 systems in brain stress tolerance
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