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Diamine Put [NH 2 (CH 2 ) 4 NH 2 ], triamine Spd [NH 2 (CH 2 ) 3 NH(CH 2 ) 4 NH 2 ], tetramine Spm [NH 2 (CH 2 ) 3 NH(CH 2 ) 4 NH(CH 2 ) 3 NH 2 ] are most common PAs in higher plants which exist as soluble conjugated, and insoluble bound forms and differential forms of PAs function differently (Lefevre et al., Metal(loid)-specificity and -chelation mechanisms Literature is scarce on the specificity of amino acids and their derivatives to varied metals