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To better understand the molecular adaptations underlying evolved enantioselectivity, we obtained structures for all six high-selectivity variantsfour in complex with their cognate ligand and two in their apo formS2.3 with S -THIQ (2.1 ), S2.4 with S -THIQ (1.8 ), D2.3 with DHIQ (2.4 ), R2.1 with R -THIQ (2.5 ), D2.1 apo (1.9 ) and R2.2 apo (4.0
This is because both compounds affect gastrointestinal motility and appetite through their respective mechanisms, and layering them too aggressively creates compounding GI effects that can derail compliance
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